Parents
- Francesco d'Este, Francesco III (1698 - 1780), duca di Modena, gouverneur de Lombardie
- Charlotte-Aglaé d'Orléans, Mademoiselle de Valois (1700 - 1761)
Family
- Married on April 16, 1741, with Maria Teresa Cybo Malaspina (1725 - 1790), issuing
Maria Beatrice (1750 - 1829)