Parents
- Leopold von Habsburg-Lothringen, Léopold Ier de Toscane (1747 - 1792), empereur des Romains
- María Luisa de Borbón (1745 - 1792), impératrice des Romains
Family
- Married on October 30, 1799 in Gatchina, with Aleksandra Pavlovna Romanov-Holstein-Gottorp (1783 - 1801), issuing
Alexandrine (1801 - 1801)
- Married on August 30, 1815, with Hermine von Anhalt-Bernburg-Schaumburg-Hoym (1797 - 1817)
- Married on August 24, 1819 in Vienna, with Maria Dorothea von Württemberg (1797 - 1855), issuing
- Franziska Marie Elisabeth (1820 - 1820)
Alexander (1825 - 1837)- Elisabeth Franziska (1831 - 1903)
- Joseph (1833 - 1905)
- Marie Henriette (1836 - 1902)